| 论文题目 | Quantitative Raman Spectroscopic Determination of the Composition, Pressure, and Density of CO2-CH4 Gas Mixtures |
| 论文题目（英文） | Quantitative Raman Spectroscopic Determination of the Composition, Pressure, and Density of CO2-CH4 Gas Mixtures |
| 作者 | 陈颖;周義明 |
| 发表年度 | 2022-09-30 |
| 卷 | 2022 |
| 期 | |
| 页码 | 18 |
| 期刊名称 | JOURNAL OF SPECTROSCOPY |
| 摘要 | |
| 摘要_英文 |
The Raman spectra for pure CO2 and CH4 gases and their ten gas mixtures were collected at pressures and temperatures ranging from 2 MPa to 40 MPa and room temperature (similar to 24 degrees C) to 300 degrees C, respectively. A systematic analysis was carried out to establish a methodology for the quantitative determination of the composition, pressure, and density of CO2-CH4 mixtures. The shift in the peak position of the upsilon(1) band for CH4 was sufficiently large to enable the accurate determination of the pressure of pure CH4 and CH4-dominated fluids (>50 mol% CH4). An equation representing the observed relationship of the peak position of the upsilon(1) band of CH4, density, and composition was developed to calculate the density of CO2-CH4 mixtures. The Raman quantification factor F (CH4)/F (CO2) was demonstrated to be near a constant value of 5.048 +/- 0.4 and was used to determine the CH4 to CO2 molar ratio in an unknown CO2-CH4-bearing fluid with high internal pressure (>10 MPa) based on the Raman peak area ratio. The effect of temperature on the variation in Raman spectral parameters was also investigated at temperatures up to 300 degrees C. The results showed that the effect of temperature must be considered when Raman spectral parameters are used to calculate the pressure, density, and composition of CO2-CH4 gas mixtures. Raman spectroscopic analysis results obtained for six samples prepared in fused silica capillary capsules were validated by comparison with the results obtained from microthermometry measurements.
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